62019-90-3

Basic information

• Product Name: Silane, (3-methyl-1-butenyl)triphenyl-, (E)-
• CAS NO: 62019-90-3
• Molecular Formula: C23H24Si
• Molecular Weight: 328.529
• Mol File: 62019-90-3.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: Silane, (3-methyl-1-butenyl)triphenyl-, (E)-(CAS DataBase Reference)
• NIST Chemistry Reference: Silane, (3-methyl-1-butenyl)triphenyl-, (E)-(62019-90-3)
• EPA Substance Registry System: Silane, (3-methyl-1-butenyl)triphenyl-, (E)-(62019-90-3)

Safety Data

• Hazardous Substances Data: 62019-90-3(Hazardous Substances Data)

Upstream product

• 6229-00-1 triphenylsilylacetylene 
• 1068-55-9 isopropylmagnesium chloride 
• 598-23-2 3-methyl-but-1-yne 
• 789-25-3 HSiPh₃ 

Relevant articles and documents

ORGANOCOPPER(I) MEDIATED SYNTHESIS OF 1-ALKENYLSILANES AND 1,3-ALKADIENYLSILANES FROM ETHYNYLSILANES

Ethynylsilanes (I) are converted into α-silyl substituted (Z)-alkenylcopper(I) compounds (II) by treatment with RCu reagents.The adducts II react with a variety of electrophiles to give the 1-alkenylsilanes RCH=C(E)SiR3' (III: E = H, Cl, Br, I, CN, SnMe3, SMe, Me, H2C=CHCH2).The conversion of I into III (E = H) can also be effected by using homocuprates, R2CuMgCl, and triorganodicuprates, R3Cu2MgCl.The latter reagent should be used when the group R is methyl.An interesting 1,3-diene formation is observed on treating excess of ethynyltrimethylsilane (Ib) with R3Cu2MgCl; this reaction involves addition of intermediary vinylcuprates to unreacted 1-alkynylsilane (Ib).The intermediary 1,3-dienyl adduct (VIIb) reacts with various electrophiles to give 1,3-dienes, RCH=C(SiMe3)CH=C(E)SiMe3 (VIIIb).