620595-41-7Relevant academic research and scientific papers
Reactivity of the labile complex [MoCl(η3-allyl)(CO) 2(NCMe)2] with diphosphanes
Perez, Julio,Morales, Dolores,Riera, Victor,Rodriguez, Amor,Garcia-Granda, Santiago
, p. 1641 - 1644 (2003)
The reactions of [MoCl(η3-allyl)(CO)2(NCMe) 2] (1) with variable ratios of bis(dimethylphosphanyl)methane (dmpm) or bis(diphenylphosphanyl)methane (dppm) afford different products, in which the diphosphanes are acting either as a chelate, as in [MoCl(η3- allyl)(CO)2(P-P)] (P-P = dmpm 2, dppm 6) and [Mo(NCMe) (η3-allyl)(CO)2(P-P)]-[{Mo(η3-allyl) (CO)2}2(μ-Cl)3] (P-P = dmpm 4, dppm 8) or as a bridge as in [{Mo(η3-allyl)(CO)2} 2(μ-Cl)2(u-P-P)] (P-P = dmpm 3, dppm 7). The analogous reaction with tetraethyldiphosphite (tedip) affords [{Mo(η3- allyl)(CO)2}2(μ-Cl)2(μ-tedip)] (5) as a single product. The Royal Society of Chemistry 2003.
