62098-46-8Relevant academic research and scientific papers
A simple, efficient alternative for highly stereoselective iodoacetoxylation of protected glycals
Gammon, David W.,Kinfe, Henok H.,De Vos, Dirk E.,Jacobs, Pierre A.,Sels, Bert F.
, p. 9533 - 9536 (2004)
Protected glycals are converted in high yields and selectivities in less than 2 h at low temperatures to 2-deoxy-2-iodoglycosyl acetates using the simple, inexpensive reagent mixture of ammonium iodide, hydrogen peroxide and acetic anhydride/acetic acid in acetonitrile. The corresponding 2-deoxy-2-bromoglycosyl acetates are obtained using ammonium bromide instead of the iodide, although longer reaction times are required and selectivities are inferior.
