62105-37-7Relevant academic research and scientific papers
The influence of the structure of tetracoordinate phosphorus acid esters on the catalytic effect of the sodium dodecyl sulfate - hexanol - water ternary reverse micellar system
Zakharova,Valeeva,Shagidullina,Kudryavtseva
, p. 1360 - 1364 (2000)
The catalytic effect of the sodium dodecyl sulfate - hexanol - water ternary reverse micellar system in the alkaline hydrolysis of O-alkyl O′-aryl chloromethylphosphonates as a function of the substrate structure was studied. The micellar effect is mainly determined by a change in the electronic properties of the substituents, while the hydrophobicity plays a secondary role. The kinetic data were examined in the framework of the pseudo-phase model of micellar catalysis. The rate constants of the reaction in the surface layer and the partition constants of the reactants were calculated.
The micellar effect of the sodium bis(2-ethylhexyl)sulfosuccinate - decane - water reverse system on the hydrolysis of phosphoric acid esters
Zakharova,Valeeva,Shagidullina,Kudryavtseva
, p. 1696 - 1698 (2007/10/03)
The reactivity of alkyl aryl chloromethylphosphonates in alkaline hydrolysis in the sodium bis(2-ethylhexyl)sulfosuccinate - decane - water reverse micellar system is mainly determined by the electronic properties of substituents and depends only slightly on their hydrophobicity.
