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Benzaldehyde, O-(methylsulfinyl)oxime is a chemical with a specific purpose. Lookchem provides you with multiple data and supplier information of this chemical.

62153-38-2

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62153-38-2 Usage

Check Digit Verification of cas no

The CAS Registry Mumber 62153-38-2 includes 8 digits separated into 3 groups by hyphens. The first part of the number,starting from the left, has 5 digits, 6,2,1,5 and 3 respectively; the second part has 2 digits, 3 and 8 respectively.
Calculate Digit Verification of CAS Registry Number 62153-38:
(7*6)+(6*2)+(5*1)+(4*5)+(3*3)+(2*3)+(1*8)=102
102 % 10 = 2
So 62153-38-2 is a valid CAS Registry Number.

62153-38-2SDS

SAFETY DATA SHEETS

According to Globally Harmonized System of Classification and Labelling of Chemicals (GHS) - Sixth revised edition

Version: 1.0

Creation Date: Aug 18, 2017

Revision Date: Aug 18, 2017

1.Identification

1.1 GHS Product identifier

Product name benzaldehyde (Z)-O-methylsulphinyloxime

1.2 Other means of identification

Product number -
Other names -

1.3 Recommended use of the chemical and restrictions on use

Identified uses For industry use only.
Uses advised against no data available

1.4 Supplier's details

1.5 Emergency phone number

Emergency phone number -
Service hours Monday to Friday, 9am-5pm (Standard time zone: UTC/GMT +8 hours).

More Details:62153-38-2 SDS

62153-38-2Relevant academic research and scientific papers

Reaction between Aldehyde Oximes and Methanesulphinyl Chloride

Banks, Malcolm R.,Brown, Charles,Hudson, Robert F.,Record, Keith A. F.

, p. 1501 - 1508 (2007/10/02)

The reactions of several (E)- and (Z)-benzaldehyde oximes with methanesulphinyl chloride at -70 deg C give benzaldehyde O-methylsulphinyloxime intermediates.These rearrange above 0 deg C to give the corresponding sulphonylimines in good yield, accompanied by minor products including nitriles and products derived from the decomposition of methanesulphinic acid.N.m.r. spectra (1H and 13C) show strong polarizations in the sulphonylimines, indicating a radical-cage mechanism.Further evidence for the involvement of radicals comes from the observation of strong e.s.r. signals.Kinetic measurements of the activation parameters support the conclusions that homolytic dissociation of the N-O bond is the major pathway in this rearrangement.

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