62170-40-5Relevant academic research and scientific papers
Cobalt-catalyzed hydrohydrazination of dienes and enynes: Access to allylic and propargylic hydrazides
Waser, Jerome,Gonzalez-Gomez, Jose C.,Nambu, Hisanori,Huber, Pascal,Carreira, Erick M.
, p. 4249 - 4252 (2007/10/03)
(Chemical Equation Presented) The cobalt-catalyzed hydrohydrazination reaction of dienes and enynes is presented. Allylic and propargylic hydrazines were obtained in synthetically useful yields (allylic amines, 60-90%; propargylic amines, 47-83%) and good chemo- and regioselectivity.
A convenient one-pot synthesis of (E)-silylated conjugated enynes from 1,1-bis(trimethylsilyl)-2-propyne and carbonyl derivatives
Pornet, Jacques,Princet, Bruno,Mevaa, Luc Mbaze,Miginiac, Leone
, p. 2099 - 2111 (2007/10/03)
1,1-Bis(trimethylsilyl)-2-propyne, prepared from propargyltrimethylsilane, was reacted, in the presence of a Lewis acid, with electrophiles (aldehydes, acetals) to afford (E)-silylated conjugated enynes.
