6219-53-0Relevant academic research and scientific papers
A new, high-yield synthesis of 3-aryl-1,2,4-triazoles
Guirado, Antonio,López-Caracena, Libertad,López-Sánchez, José I.,Sandoval, José,Vera, María,Bautista, Delia,Gálvez, Jesús
, p. 8055 - 8060 (2016/11/19)
A convenient new synthetic approach to 3-aryl-1,2,4-triazoles has been developed. Chloralamides were obtained by high yield reactions between benzamides and chloral hydrate. These reacted with a phosphorus pentachloride/phosphorus oxychloride mixture unde
SUBSTITUENT AND COORDINATION EFFECTS IN SINGLET REACTIONS OF 3-DIAZO-3H-1,2,4-TRIAZOLES WITH SUBSTITUTED BENZENES AND NITRO COMPOUNDS
Glinka, J.,Fiscus, D.,Rao, C. B.,Shechter, H.
, p. 3221 - 3224 (2007/10/02)
3-Diazo-3H-1,2,4-triazoles convert to singlet 3H-1,2,4-triazol-3-ylidenes which (1) effect directed electrophilic substitutions of benzenes and (2) coordinate with benzenoid substituents and nitro compounds to give decomposition or rearrangement products.
