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622383-01-1

2-[(dimethylphenylsilyl)methylene]hexan-1-ol is a chemical with a specific purpose. Lookchem provides you with multiple data and supplier information of this chemical.

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  • 622383-01-1 Structure

  • Basic information

    1. Product Name: 2-[(dimethylphenylsilyl)methylene]hexan-1-ol
    2. Synonyms: 2-[(dimethylphenylsilyl)methylene]hexan-1-ol
    3. CAS NO:622383-01-1
    4. Molecular Formula:
    5. Molecular Weight: 248.44
    6. EINECS: N/A
    7. Product Categories: N/A
    8. Mol File: 622383-01-1.mol

  • Chemical Properties

    1. Melting Point: N/A
    2. Boiling Point: N/A
    3. Flash Point: N/A
    4. Appearance: N/A
    5. Density: N/A
    6. Refractive Index: N/A
    7. Storage Temp.: N/A
    8. Solubility: N/A
    9. CAS DataBase Reference: 2-[(dimethylphenylsilyl)methylene]hexan-1-ol(CAS DataBase Reference)
    10. NIST Chemistry Reference: 2-[(dimethylphenylsilyl)methylene]hexan-1-ol(622383-01-1)
    11. EPA Substance Registry System: 2-[(dimethylphenylsilyl)methylene]hexan-1-ol(622383-01-1)

  • Safety Data

    1. Hazard Codes: N/A
    2. Statements: N/A
    3. Safety Statements: N/A
    4. WGK Germany:
    5. RTECS:
    6. HazardClass: N/A
    7. PackingGroup: N/A
    8. Hazardous Substances Data: 622383-01-1(Hazardous Substances Data)

622383-01-1 Usage

Check Digit Verification of cas no

The CAS Registry Mumber 622383-01-1 includes 9 digits separated into 3 groups by hyphens. The first part of the number,starting from the left, has 6 digits, 6,2,2,3,8 and 3 respectively; the second part has 2 digits, 0 and 1 respectively.
Calculate Digit Verification of CAS Registry Number 622383-01:
(8*6)+(7*2)+(6*2)+(5*3)+(4*8)+(3*3)+(2*0)+(1*1)=131
131 % 10 = 1
So 622383-01-1 is a valid CAS Registry Number.

622383-01-1Downstream Products

622383-01-1Relevant articles and documents

Fluoride-Promoted Rearrangement of Organo Silicon Compounds: A New Synthesis of 2-(Arylmethyl)aldehydes from 1-Alkynes

Aronica, Laura Antonella,Raffa, Patrizio,Caporusso, Anna Maria,Salvadori, Piero

, p. 9292 - 9298 (2003)

A new approach to 2-(arylmethyl)aldehydes 4 based upon a 1,2-anionotropic rearrangement of an aryl group is presented. The synthetic sequence begins with a silylformylation reaction of terminal acetylenes 5 with aryl and heteroaryl silanes 6, followed by treatment of the products (Z)-1 with TBAF. The optimization of the experimental conditions of the fluoride-promoted step is described, together with the synthetic potentialities of the process. A plausible mechanism of the rearrangement reaction is reported that suggests the addition of the fluoride ion to the arylsilicon moiety of β-silylalkenals (Z)-1 and the consequent migration of the aryl group to the adjacent carbon atom. Both aryl and heteroaryl substituents can rearrange without any loss of configuration. Bromofunctionalized substrates undergo an intramolecular reaction that affords exclusively carbacyclobenzyl aldehydes, further enhancing the high synthetic value of this method.

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