62240-36-2Relevant academic research and scientific papers
Synthesizing Molecules with Linear Tricyclic 5/5/5 and 6/5/5 Skeletons via [5 + 2 + 1]/Ene Strategy
Liu, Jing,Zhou, Yi,Zhu, Jiaqi,Yu, Zhi-Xiang
supporting information, p. 7566 - 7570 (2021/10/02)
Report here is the development of a [5 + 2 + 1]/ene strategy for the synthesis of molecules with linear tricyclic 5/5/5 and 6/5/5 skeletons widely found in natural products. The first step of this strategy is applying a Rh-catalyzed [5 + 2 + 1] reaction o
Acid-catalyzed synthesis of functionalized arylthio cyclopropane carbaldehydes and ketones
Porcu, Stefania,Luridiana, Alberto,Martis, Alberto,Frongia, Angelo,Sarais, Giorgia,Aitken, David J.,Boddaert, Thomas,Guillot, Regis,Secci, Francesco
supporting information, p. 13547 - 13550 (2019/01/06)
A general strategy for the synthesis of arylthio cyclopropyl carbaldehydes and ketones via a Br?nsted acid catalyzed arylthiol addition/ring contraction reaction sequence has been exploited. The procedure led to a wide panel of cyclopropyl carbaldehydes in generally high yields and with broad substrate scope. Mechanistic aspects and synthetic applications of this procedure were investigated.
