62244-84-2Relevant academic research and scientific papers
Synthesis of (Z)-nitroalkene derivatives through oxidative dehydrogenation coupling of α-aminocarbonyl compounds with nitromethane by copper catalysis
Zhu, Menghua,Chen, De,Zeng, Sheng,Xing, Chenhu,Deng, Wei,Xiang, Jiannan,Wang, Rui-Jia
supporting information, p. 3214 - 3219 (2018/07/21)
A novel copper-catalyzed cross-dehydrogenative coupling reaction of α-amino carbonyl compounds with nitromethane to synthesis of (Z)-nitroalkene derivatives has been established. (Z)-Nitroalkene derivatives are achieved through the cleavage of sp3 CsbndH bonds and formation of CsbndC double bond, with mild reaction conditions and excellent stereoselectivity.
Kinetics of Reactions of ω-Bromo-2-acetonaphthone with Pyridine and Substituted Anilines in Various Solvents
Ananthakrishnanadar, P.,Varghesedharumaraj, G.,Subramanian, S. V.
, p. 953 - 956 (2007/10/02)
Rate constants for the reactions of ω-bromo-2-acetonaphthone with aniline and pyridine in various protic and aprotic solvents have been determined at three temperatures.The rates of reaction with pyridine in simple alcohols are less than those with aniline.Values of Hammet ρ-constant have been obtained for the reactions with substituted anilines in a few solvents.Multiple correlation of log k40 deg C for the reaction with aniline in various alcohols employing several solvent parameters is highly successful.
