62291-44-5

Basic information

• Product Name: Benzoic acid, 2-(1-methylethenyl)-, methyl ester
• CAS NO: 62291-44-5
• Molecular Formula: C11H12O2
• Molecular Weight: 176.215
• Mol File: 62291-44-5.mol
• Article Data: 4

Chemical Properties

• CAS DataBase Reference: Benzoic acid, 2-(1-methylethenyl)-, methyl ester(CAS DataBase Reference)
• NIST Chemistry Reference: Benzoic acid, 2-(1-methylethenyl)-, methyl ester(62291-44-5)
• EPA Substance Registry System: Benzoic acid, 2-(1-methylethenyl)-, methyl ester(62291-44-5)

Safety Data

• Hazardous Substances Data: 62291-44-5(Hazardous Substances Data)

Upstream product

• 1077-79-8 methyl 2-acetylbenzoate 
• 1779-49-3 Methyltriphenylphosphonium bromide 
• 62291-45-6 1-lithio-2-(1-methylethenyl)benzene 
• 610-97-9 o-iodo-methyl-benzoic acid 
• 288321-56-2 1-Methyl-1-(1'-methylethenyl)silacyclobutane 
• 3609-46-9 2-(prop-1-en-2-yl)benzoic acid 
• 74-88-4 methyl iodide 

Downstream Products

• 1020726-50-4 2-[2-(1-methylethenyl)phenyl]propan-2-ol 
• 180092-32-4 [2-(1-methylethenyl)phenyl]methyl alcohol 
• 1620152-26-2 methyl 2-((1R,2R)-2-(ethoxycarbonyl)-1-methylcyclopropyl)benzoate 
• 62291-47-8 2-(1-Methylethenyl)-α,α-bis<2-(1-methylethenyl)phenyl>benzolmethanol 
• 62291-48-9 1,3-Dihydro-1,1-dimethyl-3,3-bis<2-(1-methylethenyl)phenyl>isobenzofuran 
• 62291-49-0 2-<9,10-Dihydro-10,10-dimethyl-1-(1-methylethenyl)-9-anthryl>-α,α-dimethylbenzolmethanol 

Relevant articles and documents

Copper-Catalyzed Modular Amino Oxygenation of Alkenes: Access to Diverse 1,2-Amino Oxygen-Containing Skeletons

Copper-catalyzed alkene amino oxygenation reactions using O-acylhydroxylamines have been achieved for a rapid and modular access to diverse 1,2-amino oxygen-containing molecules. This transformation is applicable to the use of alcohols, carbonyls, oximes, and thio-carboxylic acids as nucleophiles on both terminal and internal alkenes. Mild reaction conditions tolerate a wide range of functional groups, including ether, ester, amide, carbamate, and halide. The reaction protocol allows for starting with free amines as the precursor of O-benzoylhydroxylamines to eliminate their isolation and purification, contributing to broader synthetic utilities. Mechanistic investigations reveal the amino oxygenation reactions may involve distinct pathways, depending on different oxygen nucleophiles.

1-methyl-1-vinyl- and 1-methyl-1-(prop-2-enyl)silacyclobutane: Reagents for palladium-catalyzed cross-coupling reactions of aryl halides

1-Methyl-1-vinylsilacyclobutane (1) and 1-methyl-1(prop-2- enyl)silacyclobutane (2) undergo rapid and high yielding cross-coupling with aromatic halides. Many different substituents and patterns on the aromatic moiety are tolerated. All reactions can be r