62311-46-0Relevant academic research and scientific papers
Studies on the enantioselectivity of the transesterification of 2-methyl-1,4-butanediol and its derivatives catalyzed by Pseudomonas fluorescens lipase in organic solvents
Grisenti,Ferraboschi,Casati,Santaniello
, p. 997 - 1006 (1993)
The irreversible transesterification of 2-methy-1,4-butanediol 1a and its benzyl ethers 2a and 3a catalyzed by Pseudomonas fluorescens lipase in chloroform was studied, the highest ee (> 98%) having been obtained for the 4-benzyl ether 2a.
Mercury(II)-mediated cleavage of cyclopropylcarbinols by an intramolecular sulfinyl group as a stereo-and regioselective route to stereotriads and stereotetrads
Raghavan, Sadagopan,Sudheer Babu, Vaddela,Sridhar
supporting information; experimental part, p. 557 - 565 (2011/04/16)
Mercury(II) salt mediated opening of cyclopropylcarbinols by an intramolecular sulfinyl group is disclosed. All four diastereomeric stereotriads have been prepared from cis-and trans-disubstituted cyclopropanes. The trisubstituted cyclopropanes also react regio-and stereoselectively to afford products possessing quaternary stereogenic centers. The reaction is clean and general.
