62311-75-5Relevant academic research and scientific papers
THE SHERADSKY REARRANGEMENT OF α,α-DISUBSTITUTED CYCLOPENTANONE ARYLOXIMES: A SYNTHESIS OF THE SESQUITERPENES (+/-)-APLYSIN AND (+/-)-FILIFORMIN
Laronze, Jean-Yves,Boukili, Rachida El,Cartier, Dominique,Laronze, Jacqueline,Levy, Jean
, p. 2229 - 2232 (2007/10/02)
Lactols 6a,b, obtained by the Sheradsky rearrangement of aryloximes o, were alkylated in to 9a, in which three contiguous chiral centers were controlled.Cyclization of 9a gave the marine sesquiterpenes (+/-)-aplysin 11 and (+/-)-filiformin 13.
