623174-69-6Relevant academic research and scientific papers
Generation of previously unknown (alk-1-ynyl)organylthiocarbenes by the γ-elimination of HCl from 1-substituted 3-organyl-1-chloropropadienes under the action of bases
Shavrin, Konstantin N.,Gvozdev, Valentin D.,Nefedov, Oleg M.
, p. 52 - 53 (2003)
Previously unknown (alk-1-ynyl)organylthiocarbenes were generated from 1-substituted 1-chloro-3-organylthiopropadienes 1 as a result of HCl elimination under the action of potassium tert-butoxide.
(Alk-1-ynyl)organylthiocarbenes: Generation and reactions with olefins
Shavrin,Gvozdev,Pinus,Dotsenko,Nefedov
, p. 2546 - 2553 (2007/10/03)
1-Substituted 1-chloro-3-organylthiopropa-1,2-dienes 1a-f belonging to previously unknown type of allenic compounds were synthesized by chlorination of 1-organylthioalk-1-ynes 3a-f with N-chlorosuccinimide. The reactions of compounds 1a-f with But/s
