623462-14-6Relevant academic research and scientific papers
A C(aryl)-N(amine) bond atropisomeric aminophosphine: Preparation and use as a ligand in a catalytic asymmetric allylic alkylation
Mino, Takashi,Tanaka, Youichi,Yabusaki, Toshihiro,Okumura, Daisuke,Sakamoto, Masami,Fujita, Tsutomu
, p. 2503 - 2506 (2003)
The existence of 3 as a pair of stable atropisomers has been demonstrated analytically through chiral phase LC-CD investigations. Resolution of 3d was achieved by preparative chiral HPLC. Finally, the ability of the first C(aryl)-N(amine) axially chiral p
