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Bicyclo[2.2.1]heptane-2,3-dione, also known as norbornane-2,3-dione or norbornanone, is a bicyclic ketone with the molecular formula C7H8O2. It features a seven-membered ring with two carbonyl groups at positions 2 and 3, forming a norbornane core structure. This organic compound is an important intermediate in the synthesis of various pharmaceuticals, agrochemicals, and other specialty chemicals due to its unique bicyclic structure and reactivity. It can be synthesized through various methods, including Diels-Alder reactions and intramolecular cyclizations. Bicyclo[2.2.1]heptane-2,3-dione is a versatile building block in organic chemistry, offering a range of applications in the development of complex molecular architectures and functional materials.

6236-71-1

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6236-71-1 Usage

Check Digit Verification of cas no

The CAS Registry Mumber 6236-71-1 includes 7 digits separated into 3 groups by hyphens. The first part of the number,starting from the left, has 4 digits, 6,2,3 and 6 respectively; the second part has 2 digits, 7 and 1 respectively.
Calculate Digit Verification of CAS Registry Number 6236-71:
(6*6)+(5*2)+(4*3)+(3*6)+(2*7)+(1*1)=91
91 % 10 = 1
So 6236-71-1 is a valid CAS Registry Number.

6236-71-1SDS

SAFETY DATA SHEETS

According to Globally Harmonized System of Classification and Labelling of Chemicals (GHS) - Sixth revised edition

Version: 1.0

Creation Date: Aug 17, 2017

Revision Date: Aug 17, 2017

1.Identification

1.1 GHS Product identifier

Product name Bicyclo[2.2.1]heptane-2,3-dione

1.2 Other means of identification

Product number -
Other names norbornane-2,3-dione

1.3 Recommended use of the chemical and restrictions on use

Identified uses For industry use only.
Uses advised against no data available

1.4 Supplier's details

1.5 Emergency phone number

Emergency phone number -
Service hours Monday to Friday, 9am-5pm (Standard time zone: UTC/GMT +8 hours).

More Details:6236-71-1 SDS

6236-71-1Relevant academic research and scientific papers

Selective alkene oxidation with H2O2 and a heterogenized Mn catalyst: Epoxidation and a new entry to vicinal cis-diols

De Vos, Dirk E.,De Wildeman, Stefaan,Sels, Bert F.,Grobet, Piet J.,Jacobs, Pierre A.

, p. 980 - 983 (2007/10/03)

Covalent anchoring of 1,4-dimethyl-1,4,7-triazacyclononane on silica gel is the first step in the preparation of a heterogenized Mn catalyst. When H2O2 is used as the oxidant, this material can catalyze the vicinal cis- dihydroxylation of disubstituted olefins, as shown schematically here. Both enantiomers of the product are obtained.

Structural Effects Affecting Hydration of 1,2-Diones Studied by Linear-Sweep Voltammetry

Segretario, James P.,Sleszynski, Neal,Partch, Richard E.,Zuman, Petr,Horak, Vaclav

, p. 5393 - 5396 (2007/10/02)

Linear-sweep voltammetry was used for determination of values KdCO = and KdCO = +R'>+)R'> for some aliphatic and alicyclic 1,2-diketones.Values obtained were compared with data obtained from UV and NMR spectra.Dc polarographic data were used to choose the most reliable value.In all cases, the protonated form predominating in solutions of sulfuric acid is less strongly hydrated than the unprotonated form.The effect of ring size on the hydration in polycyclic species is discussed.Steric hindrance of the hydration due to the 7- and possibly the 1-methyl group in 2,3-camphorquinone has been confirmed.

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