62458-57-5

Basic information

• Product Name: (3aR)-3aα,4,5,5a,6,7,9aβ,9bα-Octahydro-5aα,9-dimethyl-3-methylenenaphtho[1,2-b]furan-2(3H)-one
• Synonyms: (3aR)-3aα,4,5,5a,6,7,9aβ,9bα-Octahydro-5aα,9-dimethyl-3-methylenenaphtho[1,2-b]furan-2(3H)-one;Isocritonilide
• CAS NO: 62458-57-5
• Molecular Formula: C15H20O2
• Molecular Weight: 232.3181
• Mol File: 62458-57-5.mol
• Article Data: 2

Chemical Properties

• Appearance: /
• CAS DataBase Reference: (3aR)-3aα,4,5,5a,6,7,9aβ,9bα-Octahydro-5aα,9-dimethyl-3-methylenenaphtho[1,2-b]furan-2(3H)-one(CAS DataBase Reference)
• NIST Chemistry Reference: (3aR)-3aα,4,5,5a,6,7,9aβ,9bα-Octahydro-5aα,9-dimethyl-3-methylenenaphtho[1,2-b]furan-2(3H)-one(62458-57-5)
• EPA Substance Registry System: (3aR)-3aα,4,5,5a,6,7,9aβ,9bα-Octahydro-5aα,9-dimethyl-3-methylenenaphtho[1,2-b]furan-2(3H)-one(62458-57-5)

Safety Data

• Hazardous Substances Data: 62458-57-5(Hazardous Substances Data)

Upstream product

• 553-21-9 costunolide 
• 108-24-7 acetic anhydride 

Relevant articles and documents

Olefin Acylation Reactions on Sesquiterpene Lactones

The olefin acylation of a variety of sesquiterpene lactones with acetic anhydride in the presence of zinc chloride as a catalyst in methylene chloride affords β,γ-unsaturated ketones of any α,β-isomers.The 1,5-cyclodecadiene system present in constunolide (XII) undergoes cyclization followed by acylation and in 11-spirocyclopropyl system cleavage of the cyclopropane occurs.