625080-50-4Relevant academic research and scientific papers
(Cyclopentadienylamine)scandium(2,3-dimethyl-1,3-butadiene): A 1,3-diene complex of scandium with Sc(I)- and Sc(III)-like reactivity
Beetstra, Dirk J.,Meetsma, Auke,Hessen, Bart,Teuben, Jan H.
, p. 4372 - 4374 (2003)
The scandium 2,3-dimethyl-1,3-butadiene complex [η5, η1-C5H4(CH2)2NMe 2]Sc(C6H10) (2) reacts with PhCN via initial nitrile insertion into the Sc-diene bond to give a dimeric μ2-imido species, but with a 2,2′-bipyridine via the elimination of the free diene. The latter shows that 2 can be used to generate the reactive fragment [η5,η1-C5H4(CH2) 2NMe2]ScI.
