625111-00-4Relevant academic research and scientific papers
Synthesis of Stannole Anion by Alkylation of Stannole Dianion
Saito, Masaichi,Haga, Ryuta,Yoshioka, Michikazu
, p. 912 - 913 (2003)
Reaction of tert-butylchloride with the stannole dianion first and simply prepared by the reduction of 1,1,2,3,4,5-hexaphenylstannole with lithium in ether gave 1-tert-butylstannole anion which was characterized by 1H, 13C, 119
Synthesis and reactions of stannole anions
Haga, Ryuta,Saito, Masaichi,Yoshioka, Michikazu
, p. 1297 - 1306 (2008/02/06)
The synthesis of stannole anions bearing various substituents on the tin atom is described. The reduction of hexaphenylstannole by the proper amount of lithium gave 1,2,3,4,5-pentaphenylstannole anion 1. The reaction of 1 with 1,n-dihaloalkanes (n = 1, 3,
Synthesis and structures of bi(1,1-stannole)s
Saito, Masaichi,Haga, Ryuta,Yoshioka, Michikazu
, p. 3750 - 3755 (2007/10/03)
The synthesis and structures of bi(1,1-stannole)s are described. Treatment of 1-bromo-4-(dibromophenylstannyl)-1,3-butadiene with tert-butyllithium gives the bi(1,1-stannole) having a phenyl group on each tin atom, whereas treatment of 1-bromo-4-(tribromostannyl)-1,3-butadiene with phenyl- or bulky alkyllithiums gives the bi(1,1-stannole) having a phenyl or an alkyl group on each tin atom. The X-ray analysis of the tert-butyl-substituted bi(1,1-stannole) is also described. All bi(1,1-stannole)s display two shoulder absorption bands due to π-π* and σ-π* transitions. Wiley-VCH Verlag GmbH & Co. KGaA, 2005.
