6252-35-3

Basic information

• Product Name: 2-(4-methyl-3-cyclohexen-1-yl)propane-1,2-diol
• Synonyms: 2-(4-methyl-3-cyclohexen-1-yl)propane-1,2-diol;EINECS 228-373-7;4-menth-1-ene-8,9-diol;UROTERPENOL;Ccris 7134
• CAS NO: 6252-35-3
• Molecular Formula: C₁₀H₁₈O₂
• Molecular Weight: 170.24872
• EINECS: 228-373-7
• Mol File: 6252-35-3.mol
• Article Data: 5

Chemical Properties

• Boiling Point: 282.7°C at 760 mmHg
• Flash Point: 131.2°C
• Appearance: /
• Density: 1.047g/cm³
• Vapor Pressure: 0.000388mmHg at 25°C
• Refractive Index: 1.51
• CAS DataBase Reference: 2-(4-methyl-3-cyclohexen-1-yl)propane-1,2-diol(CAS DataBase Reference)
• NIST Chemistry Reference: 2-(4-methyl-3-cyclohexen-1-yl)propane-1,2-diol(6252-35-3)
• EPA Substance Registry System: 2-(4-methyl-3-cyclohexen-1-yl)propane-1,2-diol(6252-35-3)

Safety Data

• Hazardous Substances Data: 6252-35-3(Hazardous Substances Data)

Usage

Appearance

Colorless organic compound.

Usage

Commonly used as a fragrance ingredient in perfumes, soaps, and other personal care products.

Natural sources

Derived from natural sources such as citrus fruits.

Aroma

Fresh, citrusy, and slightly floral.

Scent characteristics

Long-lasting and appealing.

Fragrance quality

Adds a clean and refreshing quality to fragrances.

Additional uses

Used as a flavoring agent in food products and beverages.

Antimicrobial properties

Common ingredient in antiseptic and disinfectant products.

Precaution

Can be a skin and eye irritant in its pure form and should be handled with care.

InChI:InChI=1/C10H18O2/c1-8-3-5-9(6-4-8)10(2,12)7-11/h3,9,11-12H,4-7H2,1-2H3

Upstream product

• 70238-37-8 (2'Z,6'E)-Essigsaeure-(8'-hydroxy-3',7'-dimethyl-2',6'-octadien-1'-yl)ester 
• 98-55-5 terpineol 
• 28664-18-8 2-(4-methylcyclohex-3-en-1-yl)propan-2-yl 2,2,2-trifluoroacetate 
• 10067-30-8 8,9-diacetoxy-p-menth-1-ene 
• 138-86-3 limonene. 
• 94853-00-6 (2Z,6E)-3,7-dimethyl-8-oxoocta-2,6-dien-1-yl acetate 
• 37905-02-5 (2E,6E)-3,7-dimethyl-8-oxoocta-2,6-dien-1-yl acetate 
• 105-87-3 3,7-dimethyl-2E,6-octadien-1-yl acetate 
• 141-12-8 neryl acetate 
• 106-25-2 Nerol 
• 130487-30-8 (2E,6E)-8-Benzyloxy-2,6-dimethyl-2,6-octadienyl Acetate 
• 52188-74-6 (E,E)-8-acetoxy-1-benzyloxy-3,7-dimethylocta-2,6-diene 
• 36052-53-6 trans,trans-2,6-dimethyl-2,6-octadiene-1,8-diyl diacetate 
• 10090-80-9 9-acetoxy-8-hydroxy-p-menth-1-ene 

Downstream Products

• 14675-11-7 p-menthane-8,9-diol 
• 98-55-5 terpineol 
• 72257-53-5 (-)-α2-acetyloxy-1,8-cineole 
• 72257-53-5 (+)-α2-acetyloxy-1,8-cineole 
• 18679-55-5 (+/-)-2-oxo-1,8-cineole 
• 18679-48-6 (+/-)-β2-hydroxy-1,8-cineole 
• 72257-53-5 cis-2-acetoxy-1,8-cineole 
• 72257-53-5 (+)-β2-acetyloxy-1,8-cineole 
• 72257-53-5 (-)-β2-acetyloxy-1,8-cineole 
• 72447-56-4 9-Hydroxycineole 
• 18679-48-6 2-endo-hydroxy-1,8-cineole ((1R,6R)-1,3,3-trimethyl-2-oxabicyclo-[2.2.2]octan-6-ol) 
• 72257-53-5 (+/-)-1,3,3-trimethyl-2-oxabicyclo[2.2.2]octan-6-ol acetate 
• 107090-89-1 Toluene-4-sulfonic acid 2-hydroxy-2-(4-methyl-cyclohex-3-enyl)-propyl ester 

Relevant articles and documents

Traceless Silylation of β-C(sp3)-H Bonds of Alcohols via Perfluorinated Acetals

We report the silylation of primary C-H bonds located β to secondary and tertiary alcohols by exploiting perfluorinated esters as traceless directing groups. The conversion of a secondary or tertiary alcohol to a perfluoroalkyl ester and conversion of the ester to the corresponding silyl acetals by hydrosilylation allows for selective β-C(sp3)-H silylation catalyzed by the combination of [Ir(cod)OMe]2 and Me4Phen (3,4,7,8-tetramethyl-1,10-phenanthroline) to form 6-membered dioxasilinane. Tamao-Fleming oxidation of these dioxasilinane leads to 1,2 diols. The developed sequence was applied to a series of natural products containing hydroxyl groups.

Superacidic cyclization of ω-hydroxygeraniol diacetate and ω-hydroxygeraniol benzyl ether acetate

Low-temperature superacidic cyclization of (E,E)-3,7-dimethylocta-2,6-diene-1,8-diol (ω-hydroxygeraniol) diacetate and (E,E)-8-acetoxy-1-benzyloxy-3,7-dimethylocta-2,6-diene leads to the same mixtures of two diastereomeric 9-acetoxy-8-hydroxy-p-menth-1-enes epimeric at the C(8) atom.

Terpenoids biotransformation in mammals III: Biotransformation of α-pinene, β-pinene, pinane, 3-carene, carane, myrcene, and ρ-cymene in rabbits

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