62533-70-4

Upstream product

• 100-50-5 3-Cyclohexene-1-carboxaldehyde 
• 76669-12-0 N-(Methyl)imidodithiokohlensaeure-S-benzyl-S'-methylester 

Downstream Products

• 62533-75-9 ((4S,5R)-5-Cyclohex-3-enyl-4-phenyl-[1,3]oxathiolan-2-ylidene)-dimethyl-ammonium; iodide 
• 62533-75-9 ((4R,5R)-5-Cyclohex-3-enyl-4-phenyl-[1,3]oxathiolan-2-ylidene)-dimethyl-ammonium; iodide 

Relevant academic research and scientific papers

Metalated Nitrogen Derivatives of Carbonic Acid in Organic Synthesis, XVI. - Synthesis of 2-Alkylimino- and 2-Arylimino-1,3-oxathiolanes from Lithiated S,S'-Dialkyl Imidodithiocarbonates and Carbonyl Compounds

S,S'-Dialkyl N-(methyl)-, N-(phenyl)-, or N-(cyclopropyl)imidodithiocarbonates 5 were deprotonated by means of lithium diisopropylamide.The resulting α-thio-substituted lithium alkanides 6, which are stabilized by chelatization, were trapped as trimethylsilanes 7.Reaction of 6 with aldehydes or ketones yields the title compounds 20 via adducts 18 and loss of methanethiolate.