626236-72-4

Basic information

• Product Name: 2,2'-bis((2-methylallyl)oxy)-1,1'-biphenyl
• Synonyms: 2,2'-bis((2-methylallyl)oxy)-1,1'-biphenyl
• CAS NO: 626236-72-4
• Molecular Weight: 294.393
• Mol File: 626236-72-4.mol

Chemical Properties

• CAS DataBase Reference: 2,2'-bis((2-methylallyl)oxy)-1,1'-biphenyl(CAS DataBase Reference)
• NIST Chemistry Reference: 2,2'-bis((2-methylallyl)oxy)-1,1'-biphenyl(626236-72-4)
• EPA Substance Registry System: 2,2'-bis((2-methylallyl)oxy)-1,1'-biphenyl(626236-72-4)

Safety Data

• Hazardous Substances Data: 626236-72-4(Hazardous Substances Data)

Upstream product

• 10178-53-7 1-bromo-2-((2-methylallyl)oxy)benzene 
• 2564-83-2 2,2,6,6-Tetramethyl-1-piperidinyloxy free radical 
• 32644-22-7 1-methyl-3-phenylallene 
• 1313761-30-6 (2-((2-methylallyl)oxy)phenyl)boronic acid 

Downstream Products

• 761447-78-3 3,3'-bis(2-methylallyl)-(1,1'-biphenyl)-2,2'-diol 

Relevant articles and documents

Copper-catalyzed regio- and stereoselective intermolecular three-component oxyarylation of allenes

A copper(II)-catalyzed intermolecular three-component oxyarylation of allenes using arylboronic acids as a carbon source and TEMPO as an oxygen source is described. The reaction proceeded under mild conditions with high regio- and stereoselectivity and functional group tolerance. A plausible reaction mechanism is proposed, involving carbocupration of allenes, homolysis of the intervening allylcopper(II), and a radical TEMPO trap.