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1,4-Phenylene bis(tetraethylphosphorodiamidite) is a chemical compound with the formula C18H38N2O2P2. It is a colorless liquid that is soluble in organic solvents. 1,4-phenylene bis(tetraethylphosphorodiamidite) is primarily used as a coupling agent in the synthesis of various organic compounds, particularly in the preparation of phosphoramidate derivatives. It is also employed as a reagent in the formation of phosphoramidate linkages in the synthesis of nucleic acid analogs and other biologically active molecules. Due to its reactivity and stability, 1,4-phenylene bis(tetraethylphosphorodiamidite) plays a crucial role in the field of organic chemistry and pharmaceutical research.

62701-27-3

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62701-27-3 Usage

Check Digit Verification of cas no

The CAS Registry Mumber 62701-27-3 includes 8 digits separated into 3 groups by hyphens. The first part of the number,starting from the left, has 5 digits, 6,2,7,0 and 1 respectively; the second part has 2 digits, 2 and 7 respectively.
Calculate Digit Verification of CAS Registry Number 62701-27:
(7*6)+(6*2)+(5*7)+(4*0)+(3*1)+(2*2)+(1*7)=103
103 % 10 = 3
So 62701-27-3 is a valid CAS Registry Number.

62701-27-3Relevant academic research and scientific papers

Phosphacyclophanes derived from hydroquinone and 4,4′-dihydroxybiphenyl

Nifant'ev,Rasadkina,Evdokimenkova

, p. 366 - 372 (2001)

The first representatives of linear phosphocyclophanes were prepared starting from hydroquinone or 4,4′-dihydroxybiphenyl and phosphorous triamides. The reaction course is influenced by the structures of the aromatic diol and alkyl substituents in the pho

Synthesis of the first unsymmetrical macroheterocycle containing endocyclic phosphorus atoms from pyrocatechol and hydroquinone

Blokhin,Kornilov,Volchenkova

experimental part, p. 200 - 202 (2009/08/14)

The first unsymmetrical phosphorus(III)-containing macrocycle having hydroquinone and pyrocatechol fragments, N,N,N′,N′-tetraethyl-2,4, 11,13-tetraoxa-3,12-diphosphatricyclo[12.2.2.05,10]octadeca-1(16),5, 7,9,14,17 hexaene-3,12-diamine, was syn

Synthesis of unsymmetrical phosphorus-containing macrocycles on the basis of hydroquinone, 4,4'-(propane-2,2-diyl)diphenol and resorcinol

Blokhin,Kornilov,Volchenkova

experimental part, p. 900 - 903 (2009/12/26)

Bisphosphorylation of hydroquinone and 4,4'-(propane-2,2-diyl)diphenol was performed for the first time in ethyl acetate. The bisphosphorylated products were used in molecular assembly of unsymmetrical phosphorus(III)-containing macrocycles consisting of

Dismutation of arylene phosphorodiamidites: Specific features and aspects of preparative use

Rasadkina,Slitikov,Nifant'ev

, p. 183 - 197 (2008/02/08)

The dismutation of arylene phosphorodiamidites derived from the simplest phenols and naphthols and of their dibasic analogs was studied. The main regular trends of this process and the limits of its synthetic applicability were determined. Pleiades Publishing, Inc., 2006.

SYNTHESIS AND TRANSFORMATIONS OF p-PHENYLENEBIS(PHOSPHORODIAMIDITES)

Blokhin, Yu. I.,Galiaskarova, F. M.,Ergashov, M. Ya.,Antipin, M. Yu.,Struchkov, Yu. T.,Nifant'ev, E. E.

, p. 178 - 181 (2007/10/03)

Phosphorylation of hydroquinone gave p-phenylene bis(phosphorodiamidites) and p-phenylene bis(phenylphosphonamidites).The behavior of these compounds in oxidation and complex formation was studied, as well as the use of them as phosphorylating agents.

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