62701-99-9

Upstream product

• 98-53-3 4-tercbutyl-cyclohexanone 
• 2524-64-3 chlorophosphoric acid diphenyl ester 
• 20826-82-8 Lithium; 4-tert-butyl-cyclohex-1-enolate 

Downstream Products

• 76794-69-9 1-(2-phenylethynyl)-4-tert-butyl-1-cyclohexene 
• 1189371-34-3 4-tert-butyl-N-hexylcyclohex-1-enecarboxamide 
• 1126639-42-6 2-(4-tert-butylcyclohex-1-enyl)benzo[d]oxazole 
• 1207429-64-8 2-(4-tert-butylcyclohex-1-enyl)-5-methylbenzo[d]oxazole 
• 23525-05-5 1-bromo-4-(tert-butyl)cyclohex-1-ene 
• 93725-77-0 1-(4-tert-butylcyclohex-1-en-1-yl)-4-methylbenzene 
• 80288-00-2 4,4-di-tert-butylbis<1-cyclohexen-1-yl> 
• 273937-88-5 1-(4-tert-butylcyclohex-1-enyl)-2-methylbenzene 
• 3419-74-7 4-tert-Butyl-1-methylcyclohex-1-en 
• 87437-02-3 (4-tert-Butyl-cyclohex-1-enyl)-dimethyl-phenyl-silane 

Relevant academic research and scientific papers

Efficient methods for enol phosphate synthesis using carbon-centred magnesium bases

Efficient conversion of ketones into kinetic enol phosphates under mild and accessible conditions has been realised using the developed methods with di-tert-butylmagnesium and bismesitylmagnesium. Optimisation of the quench protocol resulted in high yield

Aminocarbonylations of alkenyl phosphates, chlorides, bromides, and triflates with Mo(CO)6 as a solid CO source

Palladium-catalyzed aminocarbonylations of alkenyl chlorides, bromides, and triflates were investigated using Mo(CO)6 as a solid carbon monoxide source. The reactions afforded moderate to good yields producing a wide variety of acrylamides afte

CROSS-COUPLING REACTION BETWEEN ENOL PHOSPHATES AND ORGANOALUMINIUM COMPOUNDS IN THE PRESENCE OF PALLADIUM(0) CATALYST.

The title reaction in the presence of a catalytic amount of tetrakis(triphenylphosphine)palladium(0) affords alkylative coupling products in good to excellent yields in 1,2-dichloroethane at room temperature. This coupling reaction under C(sp**2)-O cleavage proceeds stereospecifically. The reaction does not affect a coexisting vinyl sulfide group. This feature enables 1,2- and 1,3-carbonyl transposition with or without alkylation via phenylthio-substituted enol phosphates.

NEW SYNTHESES OF ALLYLSILANES AND VINYLSILANES BY MEANS OF PhMe2Si-AlEt2

The reaction of allylic phosphates with the title organoaluminium reagent (PhMe2Si-AlEt2) provides allylsilanes in good yields.Cross coupling of enol phosphates with PhMe2Si-Mtl (Mtl = AlEt2 or MgMe) produces vi

CARBON-CARBON BOND FORMATION BY CROSS-COUPLING OF ENOL PHOSPHATES WITH ORGANOALUMINIUM COMPOUNDS CATALYZED BY PALLADIUM(O) COMPLEX

Trialkylaluminium-mediated alkylation of enol phosphates under the C-O bond cleavage is performed stereospecifically in the presence of a catalytic amount of Pd(PPh3)4.Alkenylation and alkynylation are also described.