627099-29-0

Basic information

• Product Name: (C₅H₄B(C₆H₅)Cl)Fe(C₅H₄SiCl₃)
• CAS NO: 627099-29-0
• Molecular Weight: 441.835
• Mol File: 627099-29-0.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: (C₅H₄B(C₆H₅)Cl)Fe(C₅H₄SiCl₃)(CAS DataBase Reference)
• NIST Chemistry Reference: (C₅H₄B(C₆H₅)Cl)Fe(C₅H₄SiCl₃)(627099-29-0)
• EPA Substance Registry System: (C₅H₄B(C₆H₅)Cl)Fe(C₅H₄SiCl₃)(627099-29-0)

Safety Data

• Hazardous Substances Data: 627099-29-0(Hazardous Substances Data)

Upstream product

• 873-51-8 phenylborondichloride 

Relevant articles and documents

1-Sila-[1]ferrocenophanes, structure and reactivity Ring-opening by reactions with boron halides

1-Sila-[1]ferrocenophanes (1-5) were studied with respect to their NMR spectroscopic parameters, in particular the coupling constants involving the carbon atom C(1) [1 J (13 C(1),13C(2,5)), 1 J (29Si, 13C(1)) and 1 J (57Fe,13C)]. The disiloxane 6, containing two 1-sila-[1]ferrocenophane units, possesses a linear Si-O-Si group, as shown by X-ray structural analysis, being different from the bent structure of the same compound that has been reported in the literature. Ring-opening reactions of the complexes 2-5 with some boron halides (PhBCl2, BCl3, BBr3 and BI3) gave the ferrocene derivatives 7-12, in which the cyclopentadienyl rings bear silyl and boryl groups, respectively. Two of these complexes (9a and 10) were treated with lithium diethylamide in a 1:1 molar ratio, and in both cases selective substitution at the boron atom was observed (13, 14). All products were characterised by their 1H-, 11B-, 13C- and 29Si-NMR data.