6271-12-1Relevant academic research and scientific papers
Indium triiodide catalyzed reductive functionalization of amides via the single-stage treatment of hydrosilanes and organosilicon nucleophiles
Inamoto, Yoshihiro,Kaga, Yuta,Nishimoto, Yoshihiro,Yasuda, Makoto,Baba, Akio
supporting information, p. 3452 - 3455 (2013/07/26)
The indium triiodide catalyzed single-stage cascade reaction of N-sulfonyl amides with hydrosilanes and two types of organosilicon nucleophiles such as silyl cyanide and silyl enolates selectively promoted deoxygenative functionalization to give α-cyanoamines and β-aminocarbonyl compounds, respectively.
Catalyzed hydroboration of allyl sulfonamides
Hamilton, Michael G.,Hughes, Catrin E.,Irving, Alison M.,Vogels, Christopher M.,Westcott, Stephen A.
, p. 143 - 147 (2007/10/03)
The hydroboration of allyl sulfonamides (4-H3CC6 H4SO2NRCH2CH=CH2: R=H, 1; Ph, 2; Bz, 3) with catecholborane (HBcat) using different rhodium catalysts has been examined using multinuclear NMR spectroscopy. Reactions give complex product distributions, regardless of the choice of catalyst, arising from a competing isomerization reaction. This isomerization reaction can be used with N-substituted allyl sulfonamides 2 and 3 to give the corresponding enamines (4-H3 CC6H4SO2CH=CH2 CH3), which in turn react with HBcat to give regioselective formation of one isomer (4-H3CC6H4 SO2NRCH2CH2(Bcat)CH3).
