6271-53-0Relevant academic research and scientific papers
Bromobismuthates of 1,1'-(1,N-Alkanediyl)bis(picolines): Synthesis, Thermal Stability, Crystal Structures, and Optical Properties
Buikin, P. A.,Ilyukhin, A. B.,Kotov, V. Yu.,Rudenko, A. Yu.,Simonenko, N. P.,Yorov, Kh. E.
, p. 111 - 118 (2020)
Abstract: Hybrid bromobismuthates of N-alkylated derivatives of 2- and 3-methylpyridine, (C15H20N2)2Bi2Br10 (I), (C17H24N2)2Bi2Br10 (II), (C18H26N2)3(Bi2Br9)2 (III), (C14H18N2)(H3O)BiBr6 ? 2H2O (IV), (C14H18N2)2BiBr6IBr2 (V), (C16H22N2)3(Bi2Br9)2 (VI), and (C18H26N2)3(Bi2Br9)2 (VII), are synthesized in concentrated HBr and characterized by physicochemical methods. The structures of complexes I–VII are studied by X-ray structure analysis (CIF files CCDC nos. 1946844–1946850). Complexes I and II contain anions [Bi2Br10]4–. Anions [Bi2Br9]3– are found in the structures of compounds III, VI, and VII. Bis(3-methyl-1-pyridino)ethane bromobismuthate IV contains cations H3O+ and anions [BiBr6]3– and, unlike other bromobismuthates, decomposes at low temperatures. In presence of HI vapors, double bromobismuthate V containing the [BiBr6]3– and IBr2 – anions crystallizes along with compound IV.
Synthesis of some bischromophoric dyes containing nonabsorbing flexible bridge
Mishra, J K,Behera, P K,Parida, S K,Mishra, B K
, p. 118 - 122 (2007/10/02)
Bis-chromophoric dyes (9-68) having nonabsorbing flexible bridges have been synthesised by the condensation of 1,1'-alkylenebis (α/γ picolinium bromides) (1-8) with aromatic aldehydes.
REACTION OF 1,3-DIBROMOPROPANE WITH 2-,3-, AND 4-PICOLINES AND WITH 4-METHYLQUINOLINE
Kharitonov, G. V.,Ch'in, Lieh
, p. 2044 - 2046 (2007/10/02)
New trimethylenepicolinium and trimethylene-4-methylquinolinium mono- and diquaternary salts were synthesized.The structures of the synthesized compounds were confirmed by IR and UV spectroscopy.
