627101-49-9Relevant articles and documents
Stereocontrolled Total Synthesis of (-)-Callipeltoside A
Paterson, Ian,Davies, Robert D. M.,Heimann, Annekatrin C.,Marquez, Rodolfo,Meyer, Arndt
, p. 4477 - 4480 (2007/10/03)
(Equation presented) A highly stereocontrolled total synthesis of the cytotoxic macrolide (-)-callipeltoside A has been achieved in 23 steps (4.8% overall). Notable features include a novel asymmetric vinylogous aldol reaction to install the C13 stereocen