62761-91-5Relevant academic research and scientific papers
Stereoselective synthesis of (E)-2-alkyl and 2-phenyl-1-silylvinyl sulfides via hydrozirconation of alkyl silyl acetylenes
Zhong, Ping,Guo, Meng-Ping,Huang, Xian
, p. 298 - 299 (2007/10/03)
Hydrozirconation of alkyl silyl acetylenes gave organozirconium complexes, which reacted with aryl or alkyl sulfonyl chlorides to afford (E)- 1-silylvinyl sulfides in high yields.
A highly stereoselective synthesis of (z)-1-phenylthio-1-trialkyl- silylalkenes from 1-methoxy-1-phenylthio-1 - trialkylsilylalkanes
Mandai, Tadakatsu,Kohama, Makoto,Sato, Hiroaki,Kawada, Mikio,Tsuji, Jiro
, p. 4553 - 4562 (2007/10/02)
A new method for the highly stereoselective synthesis of (Z) -1-phenylthio-1-trialkylsilylalkenes 3 by the elimination of methanol from 1-methoxy-1-phenylthio-1-trialkylsilylalkane 2 in organic solvents is described.
