62834-91-7Relevant academic research and scientific papers
Catalyzed Reactions of Enol Ethers with SN1 Active Groups: A Novel Method for the Preparation of α-Alkylated Ketones
Gansaeuer, Andreas,Fielenbach, Doris,Stock, Christoph,Geich-Gimbel, Daniel
, p. 1017 - 1030 (2003)
The performance of tert-alkylations, alkoxyalkylations, and aldehyde enolate allylations proceeding with low catalyst loading (0.1 mol % - 5 mol %) is described. The reactions are complete within short times and can even be performed without solvent and under ambient conditions. The mechanism of the reaction was investigated by deuterium labeling and cross-over studies.
Catalyzed Reactions of Enolates and Cations: A Novel Method for Enolate Alkylation
Gansaeuer, Andreas,Fielenbach, Doris,Stock, Christoph
, p. 845 - 848 (2007/10/03)
The first tertiary alkylations, alkoxyalkylations, and aldehyde enolate allylations are described proceeding with low catalyst loading (0.1 mol % to 5 mol %). The reactions proceed in short times, can be performed without solvent and under ambient conditions.
