62847-80-7Relevant academic research and scientific papers
Synthesis of monosaccharide-fused azetidines
Michaud, Thierry,Chanet-Ray, Josette,Chou, Sithan,Gelas, Jacques
, p. 253 - 269 (2007/10/03)
Primary amines reacted upon 4,6-ditosylates of glucopyranosides to give an azetidine ring fused on C-4 and C-6 of the pyranose ring. On the other hand, the 4,6-ditosylate of benzyl mannopyranoside led to the 4,6-diamino-4,6-dideoxy derivative in a good yield. All the compounds and their precursors were identified by 1H and 13C NMR spectroscopy. Assignments of proton signals were made unambiguously using homodecoupling experiments.
