62849-51-8Relevant academic research and scientific papers
Synthesis of the cyclopentadienone rhodium complexes and investigation of their catalytic activity in the reductive amination of aldehydes in the presence of carbon monoxide
Pototskiy, Roman A.,Afanasyev, Oleg I.,Nelyubina, Yulia V.,Chusov, Denis,Kudinov, Alexander R.,Perekalin, Dmitry S.
, p. 6 - 11 (2017)
Reaction of bis(p-tolyl-propargyl)-tosylamide with [(cod)RhCl]2in the presence of CO gives the cyclopentadienone complex [(Cpd’)Rh(CO)Cl]n(Cpd’ = TsN(CH2)2C4(Tol)2CO). Its dissolution in DM
Solvent- and catalyst-free direct reductive amination of aldehydes and ketones with Hantzsch ester: Synthesis of secondary and tertiary amines
Nguyen, Quynh Pham Bao,Kim, Taek Hyeon
, p. 4938 - 4943 (2013/07/25)
A facile and rapid method for the parallel synthesis of a series of secondary and tertiary amines by the direct reductive amination of aldehydes and ketones with Hantzsch ester under solvent- and catalyst-free has been developed. The scope and limitation of this method are described.
