62850-21-9Relevant articles and documents
Brownstein,S.,Dunogues,J.
, p. 2073 (1977)
Aliphatic Azo Compounds, XV cis- and trans-Tetracyclopropyl- and Tetra-tert-butylazomethanes
Bernloehr, Werner,Flamm-ter Meer, Manuela A.,Kaiser, Juergen H.,Schmittel, Michael,Beckhaus, Hans-Dieter,Ruechardt, Christoph
, p. 1911 - 1918 (2007/10/02)
The products and the kinetics of the thermolysis of the title compounds 3 and 5 were investigated.Like the trans-isomers, the cis-azo compounds also undergo homolytic decomposition without accompanying cis-trans-isomerization.The observed structure-reactivity relationships are discussed.On irradiation of trans-tetra-tert-butylazomethane (trans-5) at 60-120 deg C in benzene or chlorobenzene an almost quantitative yield of 1,1,2,2-tetra-tert-butylethane is obtained.