6290-13-7Relevant articles and documents
Consecutive addition esterification and hydrolysis of cyclic olefins catalyzed by multi-SO3H functionalized multi heteropolyanion-based ionic hybrids undersolvent-free conditions
Zheng, Guocai,Li, Xinzhong
, p. 933 - 941 (2019/03/17)
An efficient protocol for the synthesis of cycloalkyl carboxylates and alcohols from cyclic olefins is described. The cyclic olefins were converted to corresponding target molecules under solvent-free conditions catalyzed by two novel multi-SO3H functionalized multi heteropolyanion-based ionic hybrids through one-pot consecutive addition esterification and hydrolysis reactions. This approach has several advantages, including high yield, simple workup and simple purification.
Ruthenium pincer-catalyzed acylation of alcohols using esters with liberation of hydrogen under neutral conditions
Gnanaprakasam, Boopathy,Ben-David, Yehoshoa,Milstein, David
supporting information; experimental part, p. 3169 - 3173 (2011/02/23)
Acylation of secondary alcohols using non-activated esters, in particular symmetrical esters (such as ethyl acetate), is achieved under neutral conditions with the liberation of molecular hydrogen. This unprecedented, environmentally benign reaction is homogenously catalyzed by a dearomatized ruthenium pincer PNN complex. Copyright
