6291-33-4Relevant academic research and scientific papers
PALLADIUM-CATALYZED ADDITION REACTION OF POLYHALOALKANES TO OLEFINS
Tsuji, Jiro,Sato, Koji,Nagashima, Hideo
, p. 393 - 398 (2007/10/02)
Pd(OAc)2 combined with phosphines catalyzes homolytic cleavage of the C-Cl bond of CCl4 and CCl3CO2CH3 leading to facile addition to olefins under mild conditions.BrCCl3 also reacts with olefins to give 1,1,1-trichloro-3-bromoalkanes.The reaction is accel
ACTIVATION OF POLYHALOALKANES BY PALLADIUM CATALYST. FACILE ADDITION OF POLYHALOALKANES TO OLEFINS
Tsuji, Jiro,Sato, Koji,Nagashima, Hideo
, p. 1169 - 1170 (2007/10/02)
Addition reaction of CCl4, CCl3Br, and CCl3CO2Me to olefins proceeded under mild conditions to afford 1 : 1 adduct in high yields by using palladium-phosphine complexes as a catalyst in the presence of bases.The reaction proceeded even at room temperature
