62922-45-6Relevant articles and documents
Bis(β-hydroxyethylthio)-C1 -C4 -alkylamines
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, (2008/06/13)
This application relates to intermediates useful for the preparation of fiber-reactive dyes, said intermediates having the formulae STR1 in which B is a --(CH2)n -- or --O--(CH2)n -- radical, where n is 1 to 6; Q is selected from the group consisting of hydrogen, C1 -C4 alkyl, C1 -C4 alkoxy, halogen, carboxyl and sulfo; and A is an amino substituent of the formula STR2 and Z and Z', independently of one another, are β-sulfatoethyl, β-thiosulfatoethyl, β-phosphatoethyl, β-acyloxyethyl, β-haloethyl or vinyl.
Preparation of N-alkenyl-2-aminomethyl-pyrrolidines
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, (2008/06/13)
An N-alkenyl-2-aminomethyl-pyrrolidine is prepared by firstly reacting tetrahydrofurfurylamine with gaseous hydrochloric acid and thionyl chloride to produce 2,5 dichloropentylamine hydrochloride. This is acetylized, possibly by acetyl chloride in dichloroethane in the presence of triethylamine, into N-acetyl-2,5-dichloropentylamine which is condensed with an alkenylamine into an N-alkenyl-2-acetylaminomethyl pyrrolidine from which the acetyl group is separated, for example by boiling with concentrated hydrochloric acid.