62981-80-0Relevant articles and documents
Tricyclic furo[2, 3-d]pyrimidone compounds and application thereof
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Paragraph 0096-0097, (2021/07/14)
The invention relates to compounds. Cyanoethyl acetate and chloroacetone with different substituent groups are used as initial raw materials, a cyanoethyl ester compound is generated under the action of sodium ethoxide, then furan compounds are generated
SYNTHESIS OF ESTERS OF 2-SUBSTITUTED 4-KETOPENTANOIC ACIDS BY THE ALKYLATION OF CH-ACIDS USING CHLOROACETONE UNDER PHASE TRANSFER CATALYSIS CONDITIONS
Sizov, A. Yu.,Yanovskaya, L. A.,Dombrovskii, V. A.
, p. 410 - 411 (2007/10/02)
An improved method was developed for the synthesis of ethyl esters of 2-substituted 4-ketopentanoic acids by the alkylation of CH2(X)CO2Et using chloroacetone in the liquid-solid KOH (K2CO3 or Na2CO3)-DMF-PhCH2(Et)3NCl system.
3-Chloro-2-(trimethylsiloxy)-1-propene as an Electrophilic Acetonyl Equivalent. A Novel Regioselective Synthesis of 1,4-Dicarbonyl Compounds
Hosomi, Akira,Shirahata, Akihiko,Araki, Yoshitaka,Sakurai, Hideki
, p. 4631 - 4633 (2007/10/02)
α-Metalated imines, hydrazones, and activated methylene compounds are acetonylated with 3-chloro-2-(trimethylsiloxy)-1-propene in high yield.Highly regioselective acetonylation at either the tertiary or secondary α-carbon of 2-methylcyclohexanone can be carried out by selecting the reaction conditions.
