62984-77-4

Upstream product

• 201230-82-2 carbon monoxide 
• 696-62-8 para-iodoanisole 
• 104-92-7 1-bromo-4-methoxy-benzene 
• 109163-43-1 4-methoxy-N-(4-methoxybenzyl)benzamide 
• 2393-23-9 4-methoxy-benzylamine 
• 100-09-4 4-methoxybenzoic acid 
• 68-12-2 N,N-dimethyl-formamide 
• 6932-13-4 4-methoxy-N-(4-methoxy-benzoyl)-benzamidine 

Relevant academic research and scientific papers

Synthesis of imides and benzoylureas by direct oxidation of N-methylenes of amides and benzylureas

Some amides and benzylureas can be oxidised to imides and benzoylureas, respectively, using silver(I) nitrate (20 mol %), copper(II) sulfate pentahydrate (20 mol %), ammonium persulfate (3.0 equiv.), and potassium fluoride (20 equiv.) in water at room temperature.

Incorporation of molecular nitrogen into organic compounds III. Reaction of titanium-nitrogen complexes with acid halides and acid anhydrides

The titanium-nitrogen complex 1, prepared from TiCl3 or TiCl4 and Mg in THF under nitrogen reacts with acid chloride to give amide and/or imide.The cyclic imides were obtained by the reaction of titanium-isocyanate complex 3, , made from titanium-nitrogen complex 1 and carbon dioxide, and the corresponding cyclic acid anhydrides.Benzoxazone derivatives afforded the corresponding quinazoline derivatives in a similar procedure.These results indicate that molecular nitrogen was incorporated into organic compounds via titanium nitrogen complexes.