63012-62-4Relevant articles and documents
Closely stacked oligo(phenylene ethynylene)s: Effect of π-stacking on the electronic properties of conjugated chromophores
Jagtap, Subodh P.,Mukhopadhyay, Sukrit,Coropceanu, Veaceslav,Brizius, Glen L.,Bredas, Jean-Luc,Collard, David M.
, p. 7176 - 7185 (2012)
In this work, a bicyclo[4.4.1]undecane scaffold is used to hold oligo(phenylene ethynylene) units in a cofacially stacked arrangement along the entire length of the conjugated units. We study the impact that the resulting strong interchain interactions ha
Efficient synthesis of substituted benzenes from 1,3-dienes or 1,4 cyclohexadienes with KMnO4 under mild conditions
McBride, Christopher M.,Chrisman, Will,Harris, Clifford E.,Singaram, Bakthan
, p. 45 - 48 (2007/10/03)
Potassium permanganate absorbed on alumina is used to oxidize 1,4- cyclohexadienes to the corresponding aromatic compounds. Intermolecular Diels-Alder reactions followed by dehydrogenation of the products with potassium permanganate supported on alumina gives an efficient two step synthesis of highly substituted aromatic compounds from acyclic precursors.