63017-58-3Relevant academic research and scientific papers
Palladium(II) acetate in pyridine as an effective catalyst for highly regioselective hydroselenation of alkynes
Kamiya, Ikuyo,Nishinaka, Etsuyo,Ogawa, Akiya
, p. 696 - 698 (2007/10/03)
(Chemical Equation Presented) A highly regioselective hydroselenation of terminal alkynes with benzeneselenol can be achieved by the combination of palladium acetate and pyridine, providing the corresponding terminal alkenes, (i.e., 2-phenylseleno-1-alkenes) as a sole product. In this hydroselenation, pyridine may act as a suitable ligand for active palladium intermediates.
The first example of transitionmetal-catalyzed hydroselenation of acetylenes
Kuniyasu, Hitoshi,Ogawa, Akiya,Sato, Ken-Ichiro,Ryu, Iihyong,Sonoda, Noboru
, p. 5525 - 5528 (2007/10/02)
A variety of transition metal complexes catalyzed the regioselective hydroselenation of acetylenes. In particular, the palladium acetate-catalyzed reaction afforded the Markovnikov adducts with high selectivity.
