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1-[bis(ethylsulfanyl)methyl]-4-chloro-benzene is a chemical with a specific purpose. Lookchem provides you with multiple data and supplier information of this chemical.

6302-92-7

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6302-92-7 Usage

Synthesis Reference(s)

Tetrahedron Letters, 32, p. 2039, 1991 DOI: 10.1016/S0040-4039(00)78902-7

Check Digit Verification of cas no

The CAS Registry Mumber 6302-92-7 includes 7 digits separated into 3 groups by hyphens. The first part of the number,starting from the left, has 4 digits, 6,3,0 and 2 respectively; the second part has 2 digits, 9 and 2 respectively.
Calculate Digit Verification of CAS Registry Number 6302-92:
(6*6)+(5*3)+(4*0)+(3*2)+(2*9)+(1*2)=77
77 % 10 = 7
So 6302-92-7 is a valid CAS Registry Number.
InChI:InChI=1/C11H15ClS2/c1-3-13-11(14-4-2)9-5-7-10(12)8-6-9/h5-8,11H,3-4H2,1-2H3

6302-92-7SDS

SAFETY DATA SHEETS

According to Globally Harmonized System of Classification and Labelling of Chemicals (GHS) - Sixth revised edition

Version: 1.0

Creation Date: Aug 12, 2017

Revision Date: Aug 12, 2017

1.Identification

1.1 GHS Product identifier

Product name 1-[bis(ethylsulfanyl)methyl]-4-chlorobenzene

1.2 Other means of identification

Product number -
Other names p-Chlor-benzaldehyd-diethyl-dithioacetal

1.3 Recommended use of the chemical and restrictions on use

Identified uses For industry use only.
Uses advised against no data available

1.4 Supplier's details

1.5 Emergency phone number

Emergency phone number -
Service hours Monday to Friday, 9am-5pm (Standard time zone: UTC/GMT +8 hours).

More Details:6302-92-7 SDS

6302-92-7Relevant articles and documents

Ethyl lactate mediated thioacetalization of aldehydes at ambient temperature

Wan, Jie-Ping,Jing, Yanfeng,Liu, Yunyun

, p. 1302 - 1305 (2016/09/28)

Dithioacetalization reactions of aldehydes with thiols/thiophenols have been successfully achieved at room temperature by employing the green, bio-based ethyl lactate as the reaction medium. By means of this sustainable approach, a class of dithioacetals has been acquired with high diversity and efficiency.

Cyanuric chloride-catalyzed thioacetalization for organocatalytic synthesis of thioacetals

Liu, Yaqin

, p. 679 - 682 (2016/05/09)

The thioacetalization of aromatic aldehydes has been realized with broad diversity in the presence of various thiols and thiophenols using cyanuric chloride as an organocatalyst.

Silica-supported phosphorus pentoxide: A reusable catalyst for S,S-acetalization of carbonyl groups under ambient conditions

Shaterian, Hamid Reza,Azizi, Kobra,Fahimi, Nafiseh

experimental part, p. 85 - 91 (2012/01/06)

Phosphorus pentoxide supported on silica gel (P2O 5/SiO2) efficiently acts as a highly active and reusable catalyst for cyclic and non-cyclic S,S-acetalization of a variety of carbonyl compounds under mild, solvent-free an

Hafnium trifluoromethanesulfonate (hafnium triflate) as a highly efficient catalyst for chemoselective thioacetalization and transthioacetalization of carbonyl compounds

Wu, Yan-Chao,Zhu, Jieping

supporting information; experimental part, p. 9522 - 9524 (2009/04/06)

(Chemical Equation Presented) A range of carbonyl compounds including aliphatic and aromatic aldehydes and ketones were converted to the corresponding thioacetals in high yields in the presence of a catalytic amount of hafnium trifluoromethanesulfonate (0.1 mol %, room temperature). The mild conditions tolerated various sensitive functional and protecting groups and were racemization-free when applied to α-aminoaldehydes. Transacetalization and chemoselective thioacetalization of aromatic aldehydes in the presence of aliphatic aldehydes and ketones were also documented.

GaCI3- and TiCl4-catalyzed insertion of isocyanides into a C-S bond of dithioacetals

Tobisu, Mamoru,Ito, Sana,Kitajima, Aki,Chatani, Naoto

supporting information; body text, p. 5223 - 5225 (2009/06/18)

(Chemical Equation Presented) The insertion reaction of isocyanide into a C-S bond of dithioacetals is catalyzed by GaCl3 or TiCl4 to afford thioimidates containing an a-alkylthio group. Balanced thiophilicity of these Lewis acids is

A mild and chemoselective dithioacetalization of aldehydes in the presence of anhydrous copper (II) sulfate

Moghaddam, Firouz Matloubi,Bardajee, Ghasem Rezanejade,Oskui, Afsane Arefi

, p. 1445 - 1450 (2007/10/03)

Various aldehydes have been protected with different thiols as dithioacetals with excellent yields using anhydrous copper sulfate as a mild and chemoselective catalyst. The reaction is carried out in a solvent and/or under solvent-free conditions. The transthioacetalization of oxyacetals into dithioacetals was also achieved in an excellent yield. Copyright Taylor & Francis Group, LLC.

Simple, mild and efficient thioacetalization and transthioacetalization of carbonyl compounds and deprotection of thioacetals: Unique role of thiols in the selectivity of thioacetalization

Das, Biswanath,Ramu, Ravirala,Reddy, Majjigapu Ravinder,Mahender, Gurram

, p. 250 - 254 (2007/10/03)

Silica supported sodium hydrogen sulfate (NaHSO4·SiO 2) has been employed for efficient thioacetalization and transthioacetalization of carbonyl compounds in CH2Cl2 at room temperature. Selectivity of thioacetalization was dependent on the thiols used for the conversion. The same catalyst was also found to be effective for deprotection of thioacetals in CH2Cl2-H2O at room temperature.

Ruthenium(III) chloride-catalyzed thioacetalization of carbonyl compounds: Scope, selectivity, and limitations

De, Surya Kanta

, p. 673 - 676 (2007/10/03)

A variety of carbonyl compounds can be easily and rapidly converted to the corresponding cyclic and acylic dithioacetals in the presence of a catalytic amount of ruthenium chloride in acetonitrile at room temperature. Some of the major advantages of this

Investigations towards the chemoselective thioacetaliztion of carbonyl compounds by using ionic liquid [bmim]Br as a recyclable catalytic medium

Kamal, Ahmed,Chouhan, Gagan

, p. 579 - 582 (2007/10/03)

The ionic liquid based on the 1-n-butyl-3-methylimidazolium cation has been prepared and used as an efficient catalytic medum for the chemoselective thioacetalization of carbonyl compounds. Furthermore, recycling and reuse of this ionic liquid medium has

Pr(OTf)3 as an efficient and recyclable catalyst for chemoselective thioacetalization of aldehydes

De, Surya Kanta

, p. 2837 - 2840 (2007/10/03)

Praseodymium triflate has been found to be an efficient and recyclable catalyst for chemoselective protection of aldehydes.

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