63035-82-5Relevant academic research and scientific papers
Homolytic Rearrangements of Ketenimines to Nitriles: Employments of Hammett Dual Parameters
Kim, Sung Soo,Liu, Bo,Park, Chul Hyun,Lee, Kwang Ho
, p. 1571 - 1573 (2007/10/03)
The thermal isomerizations of ketenimines to nitriles involve a "homolytic" transition state (TS) as the major contributor to the structure of the TS. The rates have been fitted to Hammett dual correlations. The magnitudes of |ρ/ρ| represent the relative weights in the TS assuming homolytic character.
