63042-07-9

Basic information

• Product Name: N,N-dimethyl-4-(2-phenylhydrazinyl)aniline
• Synonyms: Benzenamine, N,N-dimethyl-4-(2-phenylhydrazino)-
• CAS NO: 63042-07-9
• Molecular Formula: C₁₄H₁₇N₃
• Molecular Weight: 227.3049
• Mol File: 63042-07-9.mol
• Article Data: 5

Chemical Properties

• Boiling Point: 301.7°C at 760 mmHg
• Flash Point: 135.1°C
• Density: 1.17g/cm³
• Vapor Pressure: 0.00104mmHg at 25°C
• Refractive Index: 1.695
• CAS DataBase Reference: N,N-dimethyl-4-(2-phenylhydrazinyl)aniline(CAS DataBase Reference)
• NIST Chemistry Reference: N,N-dimethyl-4-(2-phenylhydrazinyl)aniline(63042-07-9)
• EPA Substance Registry System: N,N-dimethyl-4-(2-phenylhydrazinyl)aniline(63042-07-9)

Safety Data

• Hazardous Substances Data: 63042-07-9(Hazardous Substances Data)

Upstream product

• 60-11-7 methyl yellow 
• 60-11-7 methyl yellow 

Downstream Products

• 99-98-9 4-amino-N,N-dimethylaniline 
• 62-53-3 aniline 
• 60-11-7 methyl yellow 

Relevant articles and documents

Transfer Hydrogenation of Azo Compounds with Ammonia Borane Using a Simple Acyclic Phosphite Precatalyst

Tris(quinolin-8-yl)phosphite, P(Oquin)3, promotes the dehydrogenation of H3N·BH3 (AB) and the transfer hydrogenation of azoarenes using ammonia borane (AB) as H2 source. The metal-free reduction of azoarenes proceeds under mild reaction conditions upon which several diphenylhydrazine derivatives are obtained in high yields. The reactivity of P(Oquin)3 toward AB was evaluated through NMR in situ tests. The rate of the reaction, activation parameters, deuterium kinetic isotope effect (DKIE) and linear-free energy relationship were investigated. Such mechanistic and kinetic studies suggest that P(Oquin)3 is a precatalyst and that AB is likely involved in more than one stage of the reaction pathway. Furthermore, the kinetic data indicate that the reaction proceeds through an ordered transition state, possibly associative.

Tuning the reduction power of supported gold nanoparticle photocatalysts for selective reductions by manipulating the wavelength of visible light irradiation

Gold nanoparticles supported on CeO2 were found to be efficient photocatalysts for three selective reductions of organic compounds at ambient temperatures, under irradiation of visible light; their reduction ability can be tuned by manipulating the irradiation wavelength.

AN EFFECT TRIFLUOROMETHYL GROUP ON PHOTOSENSITIZING BEHAVIOR OF BENZOPHENONE DERIVATIVES

2,2'-Bis(trifluoromethyl)benzophenone acted as an efficient and stable photosensitizer in energy transfer and hydrogen transfer reactions.