6305-56-2

Upstream product

• 141-43-5 ethanolamine 
• 107-13-1 acrylonitrile 

Downstream Products

• 1278585-05-9 benzene-1,3,5-tricarboxylic acid tris-{2-[bis-(2-cyano-ethyl)-amino]-ethyl} ester 

Relevant academic research and scientific papers

Synthesis and Catalytic Application of Mixed Valence Iron (FeII/FeIII)-Based OMS-MIL-100(Fe) as an Efficient Green Catalyst for the aza-Michael Reaction

Abstract: In the present study, open metal site iron-based MOF [MIL-100(Fe)], by a solvothermal method with polygonal morphology, are synthesised and then applied as a heterogeneous green catalyst for aza-Michael addition of various amines with α, β-unsaturated compounds. The MIL-100(Fe) was found to be efficient, selective, green and heterogeneous catalyst for the aza-Michael reaction. The proposed catalyst has better recyclability and can be reused six times without apparent loss of activity. Graphical Abstract: [Figure not available: see fulltext.].

Convergent synthesis of polynitrile and/or polyamine dendrimers through hydroaminomethylation and Michael addition

A general concept for a versatile convergent synthesis ofpolynitrile and/or polyamine dendrimers has been developed by applying Voegtle's procedure in combination with thetandem hydroformylation/reductive amination sequence, known as hydroaminomethylation

POSITIVE RESIST COMPOSITION AND PATTERNING PROCESS

A positive resist composition comprises (A) a resin component which becomes soluble in an alkaline developer under the action of an acid and (B) an acid generator. The resin (A) is a polymer comprising recurring units containing a non-leaving hydroxyl group represented by formula (1) wherein R1 is H, methyl or trifluoromethyl, X is a single bond or methylene, m is 1 or 2, and the hydroxyl group attaches to a secondary carbon atom. The composition is improved in resolution when processed by lithography.

Aqueous aza-michael reaction of conjugated alkenes: Toward spermine

An aqueous aza-Michael reaction is efficiently achieved with excellent conversions without any additives. The method works very well on a molar scale with selectively for aliphatic amines. An intermediate for spermine is also made by this green process.

Novel tertiary (meth)acrylates having lactone structure, polymers, resist compositions and patterning process

Novel tertiary (meth)acrylate compounds having a lactone structure are polymerizable into polymers having improved transparency, especially at the exposure wavelength of an excimer laser and dry etching resistance. Resist compositions comprising the polymers are sensitive to high-energy radiation, have a high resolution, and lend themselves to micropatterning with electron beams or deep-UV rays.

Amine compounds, resist compositions and patterning process

Amine compounds having a cyano group are useful in resist compositions for preventing a resist film from thinning and also for enhancing the resolution and focus margin of resist.

Chemoselective Michael type addition of aliphatic amines to α,β-ethylenic compounds using bismuth triflate catalyst

Catalytic amounts of bismuth triflate efficiently catalyse the conjugate addition of aliphatic amines to α,β-ethylenic compounds in acetonitrile under mild conditions. The reaction is chemoselective, as aromatic amines do not participate in the reaction. Further, the catalyst can be easily recovered and reused.