63056-56-4

Basic information

• Product Name: chloro(phenylazoacetaldoximato)bis(triphenylphosphine)palladium(II)
• CAS NO: 63056-56-4
• Molecular Weight: 828.626
• Mol File: 63056-56-4.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: chloro(phenylazoacetaldoximato)bis(triphenylphosphine)palladium(II)(CAS DataBase Reference)
• NIST Chemistry Reference: chloro(phenylazoacetaldoximato)bis(triphenylphosphine)palladium(II)(63056-56-4)
• EPA Substance Registry System: chloro(phenylazoacetaldoximato)bis(triphenylphosphine)palladium(II)(63056-56-4)

Safety Data

• Hazardous Substances Data: 63056-56-4(Hazardous Substances Data)

Upstream product

• 63056-55-3 chloro(phenylazoacetaldoximato)(triphenylphosphine)palladium(II) 
• 72951-84-9 anilinechloro(phenylazoacetaldoximato)palladium(II) 
• 28966-81-6 trans-bis(triphenylphosphine)palladium dichloride 
• 63056-54-2 bis(phenylazoacetaldoximato)palladium(II) 

Downstream Products

• 28966-81-6 trans-bis(triphenylphosphine)palladium dichloride 
• 63056-55-3 chloro(phenylazoacetaldoximato)(triphenylphosphine)palladium(II) 

Relevant articles and documents

Selective Cleavage of the Two Types of Pd-N Bonds in Di-μ-halogeno-bis

Triarylphosphines split the halogen bridge of the title complex and also open the arylazo-oximato chelate ring at the azo-end.In solution an equilibrium exists between the closed-ring and open-ring species.The equilibrium constants are reported.Bidentate phosphine and phosphinoarsine simultaneously split the bridge and cleave the Pd-N(azo) bond.Anhydrous HCl gas protonates the oximato-group with its concomitant displacement by Cl-ion; in effect the Pd-N(oxime) bond is selectively cleaved.