6306-93-0Relevant articles and documents
Organoarsine Metal-Organic Framework with cis-Diarsine Pockets for the Installation of Uniquely Confined Metal Complexes
Eric Sikma,Kunal, Pranaw,Dunning, Samuel G.,Reynolds, Joseph E.,Lee, Ji Sun,Chang, Jong-San,Humphrey, Simon M.
, p. 9806 - 9809 (2018)
ACM-1 is the first example of an organoarsine metal-organic framework (MOF), prepared using a new pyridyl-functionalized triarylarsine ligand coordinated to Ni(II) nodes. ACM-1 has micropores that are decorated with cis-diarsine coordination pockets. Postsynthetic metalation of ACM-1 with AuCl under facile conditions studied by single-crystal X-ray diffraction reveals the installation of dimeric Au2Cl2 complexes via the formation of As-Au bonds. The Au(I) dimers display exceptionally short aurophilic bonds (2.76 ?) induced by the rigidity of the MOF, which acts as a unique solid-state ligand.