63148-51-6Relevant academic research and scientific papers
SYNTHESE SELECTIVE DE 1,2,4,3-TRIAZAPHOSPHOLES SUBSTITUES EN 1,5. STRUCTURE CRISTALLINE MOLECULAIRE DU 1-METHYL-5-BENZYL-4-TRIFLUOROBORO-1,2,4,3-TRIAZAPHOSPHOLE
Haddad, M.,Legros, J. P.,Lopez, L.,Boisdon, M. T.,Barrans, J.
, p. 189 - 196 (2007/10/02)
A selective synthesis of 1,5-disubstituted 1,2,4,3-triazaphosphole 3 is described from bases of Schiff of 2-N substituted amidrazones 7.Crystalline molecular structure of a triazaphosphole complex with BF3 has been determinated by X-ray diffraction.Complexation occurs on N4 nitrogen atom. Key words: 1,2,4,3-triazaphospholes; ring contraction; 15N NMR; crystal structure.
