63196-62-3

Basic information

• Product Name: Cyclohexanone, 2-ethenyl-2-methyl-
• CAS NO: 63196-62-3
• Molecular Formula: C9H14O
• Molecular Weight: 138.21
• Mol File: 63196-62-3.mol
• Article Data: 7

Chemical Properties

• CAS DataBase Reference: Cyclohexanone, 2-ethenyl-2-methyl-(CAS DataBase Reference)
• NIST Chemistry Reference: Cyclohexanone, 2-ethenyl-2-methyl-(63196-62-3)
• EPA Substance Registry System: Cyclohexanone, 2-ethenyl-2-methyl-(63196-62-3)

Safety Data

• Hazardous Substances Data: 63196-62-3(Hazardous Substances Data)

Upstream product

• 13670-84-3 2-methylcyclohexanone lithium enolate 
• 6376-95-0 trans-2-vinylcyclohexanol 
• 19980-35-9 1-trimethylsilyloxy-2-methyl-1-cyclohexene 
• 1066-54-2 trimethylsilylacetylene 
• 80533-29-5 2-<1-hydroxy-2-(phenylseleno)ethyl>-2-methylcyclohexanone 
• 1122-24-3 2-ethenylcyclohexanone 
• 74-88-4 methyl iodide 

Downstream Products

• 263860-26-0 [1R*(6R*/S*)]-[3,3-Dimethyl-1-(6-methyl-6-vinylcyclohex-1-en-1-yl)hex-5-en-1-oxy]triethylsilane 
• 287736-30-5 [1R*(6R*/S*)]-[2,2-Dimethyl-1-(6-methyl-6-vinylcyclohex-1-en-1-yl)pent-4-en-1-oxy]triethylsilane 
• 263860-25-9 [1R*(6R*/S*)]-3,3-Dimethyl-1-(6-methyl-6-vinylcyclohex-1-en-1-yl)hex-5-en-1-ol 
• 287736-29-2 [1R*(6R*/S*)]-2,2-Dimethyl-1-(6-methyl-6-vinylcyclohex-1-en-1-yl)pent-4-en-1-ol 
• 78998-92-2 1,2-diethenyl-2-methylcyclohexanol 

Relevant articles and documents

Ethenylation of silyl enol ether with silylethyne

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Dichloroketene-olefin Cycloadducts in Synthesis. A Short, Convenient, Protocol for Olefin -> α-Vinylketone Transformation

A simple, preparatively useful sequence to α-vinylketones from olefins via their -dichloroketene adducts is reported.

α Vinylation of Ketones. A General Method Using a (Phenylseleno)acetaldehyde

(Phenylseleno)acetaldehyde can be used as a synthetic equivalent of the vinyl carbonium ion, CH2=CH2+.A number of ketone enolates, usually as zinc salts, were condensed with (phenylseleno)acetaldehyde to give β-hydroxy selenides (average yield