6321-72-8Relevant articles and documents
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Aston
, p. 1448,1451, 1452 (1931)
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Mechanistic studies of electrode-assisted catalytic oxidation by flavinium and acridinium cations
Yang, Xin,Walpita, Janitha,Mirzakulova, Ekaterina,Oottikkal, Shameema,Hadad, Christopher M.,Glusac, Ksenija D.
, p. 2635 - 2644 (2014)
Electrochemical behavior of flavinium (Et-Fl+) and acridinium (Acr+) cations is presented, in order to investigate their activity toward catalytic water oxidation. Cyclic voltammograms of Acr+ and Et-Fl+ in acetonitrile are qualitatively similar, with oxidation peaks at highly positive potentials, and these oxidation peaks depend strongly on the type of the working electrode being used. However, the two model compounds exhibit different behaviors in the presence of water: while Et-Fl + facilitates electrocatalytic water oxidation through an electrode-assisted mechanism, water oxidation is not accelerated in the presence of Acr+. A comparative study of variable scan-rate cyclic voltammetry, concentration dependence, and spectroelectrochemical behavior of two model compounds suggest that Et-Fl+ and Acr+ exhibit different reaction pathways with the electrode surface. On the basis of the experimental results, a mechanism is proposed to account for the observed differences in electrocatalysis.
Mechanistic study of the photochemical hydroxide ion release from 9-hydroxy-10-methyl-9-phenyl-9,10-dihydroacridine
Zhou, Dapeng,Khatmullin, Renat,Walpita, Janitha,Miller, Nicholas A.,Luk, Hoi Ling,Vyas, Shubham,Hadad, Christopher M.,Glusac, Ksenija D.
, p. 11301 - 11303 (2012/08/27)
The excited-state behavior of 9-hydroxy-10-methyl-9-phenyl-9,10- dihydroacridine and its derivative, 9-methoxy-10-methyl-9-phenyl-9,10- dihydroacridine (AcrOR, R = H, Me), was studied via femtosecond and nanosecond UV-vis transient absorption spectroscopy. The solvent effects on C-O bond cleavage were clearly identified: a fast heterolytic cleavage (τ = 108 ps) was observed in protic solvents, while intersystem crossing was observed in aprotic solvents. Fast heterolysis generates 10-methyl-9-phenylacridinium (Acr+) and -OH, which have a long recombination lifetime (no signal decay was observed within 100 μs). AcrOH exhibits the characteristic behavior needed for its utilization as a chromophore in the pOH jump experiment.