632322-81-7

Basic information

• Product Name: Benzofuran, octahydro-2-methoxy-2-methyl-, (3aR,7aR)-rel- (9CI)
• Synonyms: Benzofuran, octahydro-2-methoxy-2-methyl-, (3aR,7aR)-rel- (9CI)
• CAS NO: 632322-81-7
• Molecular Formula: C10H18O2
• Molecular Weight: 170.24872
• Product Categories: METHOXY
• Mol File: 632322-81-7.mol
• Article Data: 3

Chemical Properties

• Appearance: /
• CAS DataBase Reference: Benzofuran, octahydro-2-methoxy-2-methyl-, (3aR,7aR)-rel- (9CI)(CAS DataBase Reference)
• NIST Chemistry Reference: Benzofuran, octahydro-2-methoxy-2-methyl-, (3aR,7aR)-rel- (9CI)(632322-81-7)
• EPA Substance Registry System: Benzofuran, octahydro-2-methoxy-2-methyl-, (3aR,7aR)-rel- (9CI)(632322-81-7)

Safety Data

• Hazardous Substances Data: 632322-81-7(Hazardous Substances Data)

Upstream product

• 822-67-3 Cyclohex-2-enol 
• 286-20-4 cyclohexane-1,2-epoxide 
• 186586-89-0 2-(2-methoxy-1-propene-3-yl)cyclohexanol 
• 632322-78-2 3-(2-Bromo-1-methoxy-1-methyl-ethoxy)-cyclohexene 

Relevant articles and documents

A radical cyclisation based cyclopentenone annulation of allyl alcohols

A four-step cyclopentenone annulation reaction of allylic alcohols employing a 5-exo-trig radical cyclisation reaction of mixed allyl methyl ketals of bromoacetone as the key step is described. The annulated product 12b obtained from 2,3-dimethylcyclohexenol has been further elaborated into (±)-epibakkenolides employing a 5-exo-dig radical cylisation reaction based α-spiro-β-methylene-γ-butyrolactone annulation methodology.

Cyclopentaannulation of Allyl Alcohols via a Radical Cyclisation Reaction. Total Synthesis of 4-Epibakkenolide-A

A four step cyclopentaannulation methodology starting from allyl alcohols using 5-exo-trig radical cyclisation as the key reaction, and its application to the total synthesis of 4-epibakkenolide is described.